The urllib module in Python 3 allows you access websites via your program. This opens up as many doors for your programs as the internet opens up for you. urllib in Python 3 is slightly different than urllib2 in Python 2, but they are mostly the same. Through urllib, you can access websites, download data, parse data, modify your headers, and do any GET and POST requests you might need to do.
Sample code for this basics series: http://pythonprogramming.net/beginner-python-programming-tutorials/
Python 3 Programming tutorial Playlist: http://www.youtube.com/watch?v=oVp1vrfL_w4&feature=share&list=PLQVvvaa0QuDe8XSftW-RAxdo6OmaeL85M